Potensi Nanokomposit [email protected] dari Bijih Besi Sebagai Pendeteksi Kadar Glukosa

Sadang Husain, Suryajaya Suryajaya, Ninis Hadi Haryanti, Tetti Novalina Manik, Rodiansono Rodiansono, Sepfina Monica Hutasoit, Agus Riyanto, Sudarningsih Sudarningsih

Abstract


Sintesis nanokomposit [email protected] dari bijih besi Tanah Laut dan sumber karbon dari gula pasir telah dilakukan dengan menggunakan metode kopresipitasi dan metode hidrotermal. Penelitian dilakukan untuk mengetahui karakteristik [email protected] berbahan bijih besi. Sebanyak 6 g bijih besi digunakan sebagai bahan baku pembuatan Fe3O4. FeSO4.7H2O digunakan sebagai sumber ion Fe2+. Sampel diaduk dengan menggunakan temperatur 70oC dengan kecepatan adukan 450 rpm. Karbon (C) disintesis menggunakan metode hidrotermal pada temperatur 300oC dengan menambahkan etilon glikol sebagai surfaktan. Sampel Fe3O4 dan C digabung pada suhu 250oC selama 30 menit dengan kecepatan 500 rpm. Sampel  Nanokomposit [email protected] dikarakterisasi menggunakan Vibrating Sample Magnetometer, Fourier Transform Infrared, Transmission Electron Microscopy, serta elektrokimia. Dari penelitian, diperoleh nilai magnetisasi saturasi sebesar 24,82 emu/g, jenis ikatan yang terdapat dalam nanokomposit [email protected] adalah ikatan Fe-O, C=O, C=N dan O-H, distribusi ukuran partikel dalam rentang 5 nm – 20 nm, dengan rata-rata ukuran partikel 12 nm, serta nilai sensitivitas 0,285 mA/ppm.


Keywords


Bijih besi, Karbon, nanokomposit [email protected]

Full Text:

PDF

References


Pauzan, M., Kato, T., Iwata, S., and Suharyadi, E., Pengaruh Ukuran Butir dan Struktur Kristal terhadap Sifat Kemagnetan pada Nanopartikel Magnetit (Fe3O4), Prosidinga Pertemuan Ilmiah XXVII HFI, pp.24–28, 2013.

Wu, R., Liu, J., Zhao, L., Zhang, X., Xie, J., Yu, B., Ma, X. , Yang, S. , Wang, H. , and Liu, Y. , Hydrothermal preparation of magnetic Fe3O4 @ C nanoparticles for dye adsorption, Biochemical Pharmacology, 2(2), pp.907–913, 2014.

Loh, K., Lee, Y. H. , Musa, A., Salmah, A. A., and Zamri, I., Use of Fe3O4 Nanoparticles for Enhancement of Biosensor Response to the Herbicide 2,4 - Dichlorophenoxyacetic Acid pp.5775–5791, 2008.

Zhang, D., Tong, Z., Li, S., Zhang, X., and Ying, A., Fabrication and characterization of hollow Fe3O4 nanospheres in a microemulsion, 62, pp.4053–4055, 2008.

Blaney, L., Magnetite (Fe3O4): Properties, Synthesis , and Applications, 15, 2007.

Martínez-mera, I., Espinosa-pesqueira, M. E., Pérez-hernández, R., and Arenas-alatorre, J., Synthesis of magnetite (Fe3O4) nanoparticles without surfactants at room temperature, 61, pp.4447–4451, 2007.

Sholihah, L.K. Sintesis dan karakterisasi partikel nano Fe3O4 yang berasal dari pasir besi dan Fe3O4 bahan komersial (aldrich). Institut Teknologi Sepuluh November, pp.2–15. (2010).

Rahmawati, R., Taufiq, A., Sunaryono, S., Fuad, A., Yuliarto, B., Suytman, S., and Kurniadi, D., Synthesis of Magnetite (Fe3O4) Nanoparticles from Iron sands by Co - precipitation - Ultrasonic Irradiation Methods, Journal of Materials and Environmental Sciences, 9(1), pp.155–160, 2018.

Rusianto, T., Wildan, M. W., Abraha, K., and Kusmono, K., Iron Sand as Renewable Resource for Production Magnetic Nano Particles Materials, Engineering International Conference 2013 Proceeding, 2013.

Partikelmagnetit, S. I. N., Dan, M., Dari, H. , and Lokal, B., Sintesis nano partikel magnetit, maghemit dan hematit dari bahan lokal, Indonesian Journal of Materials Science, pp.106–108, 2007.

Giri, S. K., Das, N. N., and Pradhan, G. C., Physicochemical and Engineering Aspects Synthesis and characterization of magnetite nanoparticles using waste iron ore tailings for adsorptive removal of dyes from aqueous solution, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 389(1–3), pp.43–49, 2011.

Wu, S., Sun, A., Zhai, F., Wang, J., Xu, W., Zhang, Q., and Volinsky, A. A., Fe3O4 magnetic nanoparticles synthesis from tailings by ultrasonic chemical, Materials Letters, 65(12), pp.1882–1884, 2011.

Mahmuda, D., Sakinah, N., and Suharyadi, E., Adsorpsi Logam Tembaga (Cu), Mangan (Mn) dan Nikel (Ni) dalam Artificial Limbah Cair dengan Menggunakan Nanopartikel Magnetit (Fe3O4), Journal of Applied Physics, 4(2), pp.126–133, 2014.

Sartika, D., Sifat Magnetik Adsorben Nanopartikan Fe3O4 Terhadap Adsorbsi Logam Berat (Co dan Fe) Dalam Larutan, Jurnal Pembelajaran Fisika, 4(5), pp.631-641, 2016.

Lanoş, R., Pǎcurariu, C., and Mihoc, G., Magnetite/carbon nanocomposites prepared by an innovative combustion synthesis technique - Excellent adsorbent materials, Ceramics International, 40(8 PART B), pp.13649–13657, 2014.

Jin, Z., Dong, Y., Dong, N., Yang, Z., Wang, Q., Lei, Z., and Su, B., One-step synthesis of magnetic nanocomposite Fe3O4/C based on the waste chicken feathers by a green solvothermal method, Materials Letters, 186(October 2016), pp.322–325, 2017.

Mamani, J. B., Gamarra, L. F., and Brito, G. E. de S., Synthesis and characterization of Fe3O4 nanoparticles with perspectives in biomedical applications, Materials Research, 17(3), pp.542–549, 2014.

Alegret, N. , Criado, A. , and Prato, M. , Recent Advances of Graphene-based Hybrids with Nanoparticles for Biomedical Applications, Current Medicinal Chemistry, 24(5), pp.529–536, 2017.

Trisnawati, L. P., Nandang, Mufti, and Zulaikah, S., Synthesizing and Characterising Carbon Encapsulated Nano Particle Fe3O4 by Using Hydrothermal Method as Textile Dye Waste Absorber Rodhamin B, 2, 2013.

Zhang, Z. and Kong, J., Novel Magnetic [email protected] Nanoparticles as Adsorbents for Removal of Organic Dyes from Aqueous Solution, Journal of Hazardous Materials, (193), pp.325–329, 2011.

Liu, J., Dong, S., He, Q., Yang, S., Xie, M., and Deng, P., Biomolecules Facile Preparation of Fe3O4/C Nanocomposite and Its Application for Cost-Effective and Sensitive Detection of Tryptophan, Biomolecules, 9(6), pp.245, 2019.

Ariyani, A., Pembuatan Komposit Magnet Oksida Besi-Karbon Aktif Sebagai Adsorben Cs Dan Sr, Institut Pertanian Bogor, 2011, 2011.

Shi, D., Yang, H., Ji, S., Jiang, S., Liu, X., and Zhang, D., Preparation and characterization of core-shell structure Fe3O4 @ C magnetic nanoparticles, Procedia Engineering, 102, pp.1555–1562, 2015.

Zysk, A. M., Marks, D. L., Liu, D. Y., and Boppart, S. A., Needle-Based Reflection Refractometry Of Scattering Samples Using Coherence-Gated Detection, Optics Express, 15(8), pp.4787–4794, 2007.

Ríos-hurtado, J. C., Múzquiz-ramos, E. M., Zugasti-cruz, A., Cortés-hernández, D. A., Químicas, F. D. C. , and Coahuila, U. A. De , Mechanosynthesis as a Simple Method to Obtain a Magnetic Composite (Activated Carbon/Fe3O4) for Hyperthermia Treatment, Journal of Biomaterials and Nanobio-technology, 7(1), pp.19–28, 2016.

Amighian, J., Mozaffari, M., and Nasr, B., Preparation of Nano-Sized Manganese Ferrite (MnFe2O4) Via Coprecipitation Method Preparation of nano-sized manganese ferrite (MnFe2O4) via coprecipitation method, Physica Status Solidi C, 3(9), 2006.

Peternele, W. S., Fuentes, V. M., Fascineli, M. L., Rodrigues, J., Silva, R. C., Lucci, C. M., and Azevedo, R. B. De , Experimental Investigation of the Coprecipitation Method : An Approach to Obtain Magnetite and Maghemite Nanoparticles with Improved Properties, Journal of Nanomaterials, 2014(1), pp.1–11, 2014.

Lopez, J. A., González, F., Bonilla, F. A., Zambrano, G., and Gómez, M. E. , Synthesis and characterization of Fe3O4 magnetic nanofluid magnetic nanofluid, Revista Latinoamericana de Metalurgia y Materiales, 30(60), pp.60–66, 2010.

Zhou, G. , Xu, S. , Li, W., and Zhang, D. , Research on the Preparation and Characterization of Magnetic Nanoparticles (MNPs) By Chemical Co-precipitation(Icimm), pp.175–180, 2016.

Sholihah, L. K., Sintesis Dan Karakteristik Partikel Nano Fe3O4 Yang Berasal Dari Pasir Besi Dan Fe3O4 Bahan Komersial (Aldrich), Institut Teknologi Sepuluh Nopember, 2010.

Pu, Y. , Tao, X. , Zeng, X. , Le, Y. , and Chen, J. , Journal of Magnetism and Magnetic Materials Synthesis of Co – Cu – Zn doped Fe 3 O 4 nanoparticles with tunable morphology and magnetic properties, Journal of Magnetism and Magnetic Materials, 322(14), pp.1985–1990, 2010.

Method, H., Preparation and characterization of magnetic nanoparticles coated with polyethylene glycol Preparation and characterization of magnetic nanoparticles coated with polyethylene glycol, pp.4–8, 2009.

Husain, S., Suarso, E., Maddu, A., and Sugianto, Karakterisasi Kandungan Bijih Besi Alam Sebagai Bahan Baku Magnetit Nanopartikel, 2016.

Rahman, T., Fadhlulloh, M. A., Nandiyanto, A. B. D., and Mudzakir, A., Review: Sintesis Karbon Nanopartikel, Integrasi Proses, 5(2), pp.61–74, 2015.

Astuti and Hasanah, A. P. I., Pengaruh Waktu Pemanasan Terhadap Sintesis Nanopartikel Fe3O4, Jurnal Ilmu Fisika, 4(1), pp.20–25, 2012.

Wang, Q., Li, H., Chen, L., and Huang, X., Monodispersed hard carbon spherules with uniform nanopores, 39(February), pp.2211–2214, 2001.

Nuzully, S., Kato, T., and Iwata, S., Pengaruh Konsentrasi Polyethylene glycol (PEG) pada Sifat Kemagnetan Nanopartikel Magnetik PEG -Coated Fe3O4, XVII, pp.35–40, 2013.

Dachriyanus, P. D., Analisis Struktur Senyawa Organik Secara Spektroskopi, LPTIK Univer-sitas Andalas, 2004.

Yu, L., Wu, H., Wu, B., Wang, Z., Cao, H., Fu, C., and Jia, N., Magnetic Fe3O4 -Reduced Graphene Oxide Nano-composites-Based Electro-chemical Biosensing, Nano-Micro, 6, pp.258–267, 2014.

Simamora, P. and Krisna In Sintesis dan Karakterisasi Sifat Magnetik Nanokomposit Fe3O4 – Montmorilonit Berdasarkan Variasi Suhu, 2015.

Liu, Y., Li, Y., Jiang, K., Tong, G., Lv, T., and Wu, W., Controllable synthesis of elliptical [email protected] and Fe3O4/[email protected] nanorings for plasmon resonance-enhanced microwave absorption, Journal of Materials Chemistry C, 4(30), pp.7316–7323, 2016.

Mendes, R., Koch, B., Bachmatiuk, A., El-Gendy, A., Krupskaya, Y., Springer, A., Klingeler, R., Schmidt, O., Buchner, B., Sanchez, S., and Rummeli, M., Synthesis and Toxicity Characterization of Carbon Coated Iron Oxide Nanoparticles with Highly Defined Size Distributions, Biochimica et Biophysica Acta, 1840, pp.160–169, 2014.

Cornel, R. M. and Schwertmann, U., The Iron Oxides: Structures, Properties, Reactions, Occurences and Uses, 1996.

Lakay, E. M., Superparamagnetic Iron-Oxide Based Nanoparticles for the Separation and Recovery of Precious Metals from Solution. University of Stellenbosch. 2009, 2009.

Irfansyah, M., Sintesis Dan Karakterisasi Elektrokimia Nanopartikel Magnetit (Fe3O4) Dari Bijih Besi. Universitas Lambung Mangkurat. 2018.




DOI: http://dx.doi.org/10.26418/positron.v9i2.32771

Refbacks

  • There are currently no refbacks.


PUBLISHED BY
IN COOPERATION WITH

Jurusan Fisika
Fakultas Matematika dan Ilmu Pengetahuan Alam
Universitas Tanjungpura
 Physical Society of Indonesia
Cabang Kalimantan Barat

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.